measurement and modeling of mean ionic activity coefficient in aqueous solution containing nano3 and poly ethylene glycol

Authors

siamak modarresi

mohammad reza dehghani

parinaz alimardani

sara kazemi sabzvar

farzaneh feyzi

abstract

potentiometric investigation on {h2o+nano3+peg1500} mixtures were made at t=308.15k, using electrochemical cells with two ion-selective electrodes, (na+ glass) as the cation ion-selective electrode against (no3- solvent-polymer pvc) as the anion ion-selective electrode. the mean ionic activity coefficients of nano3 were measured at different concentrations of  nano3 and peg. maximum concentration of electrolyte and peg were 1 mol/kg and 0.12 mol/kg, respectively. the experimental data was modeled by utilizing the modified pitzer equation and the activity coefficient ratio of peg was evaluated by using maxwell’s cross differential relation.

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Journal title:
iranian journal of chemistry and chemical engineering (ijcce)

Publisher: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

volume 32

issue 2 2013

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