measurement and modeling of mean ionic activity coefficient in aqueous solution containing nano3 and poly ethylene glycol
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abstract
potentiometric investigation on {h2o+nano3+peg1500} mixtures were made at t=308.15k, using electrochemical cells with two ion-selective electrodes, (na+ glass) as the cation ion-selective electrode against (no3- solvent-polymer pvc) as the anion ion-selective electrode. the mean ionic activity coefficients of nano3 were measured at different concentrations of nano3 and peg. maximum concentration of electrolyte and peg were 1 mol/kg and 0.12 mol/kg, respectively. the experimental data was modeled by utilizing the modified pitzer equation and the activity coefficient ratio of peg was evaluated by using maxwell’s cross differential relation.
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Journal title:
iranian journal of chemistry and chemical engineering (ijcce)Publisher: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
volume 32
issue 2 2013
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